Rank up help

Ughzy

I'm getting ready to make a bunch of rank ups and want some other opinions... first, here is what I generally run:

Questing (master, uncollected, act 5)
5 50 voodoo duped
5 50 star lord duped
5 50 luke cage duped
4 55 aa unduped
3 45 go unduped

Aq(43333)
5 50 medusa duped
3 45 ultron duped
3 45 x23 duped

Aw attack(silver 1)
5 50 switch duped
5 50 hyperion duped
3 45 elektra unduped

Aw defense
3 45 heimdall unduped
5 50 blade duped
5 50 void duped
5 50 magik duped
5 50 imiw duped

I'm gonna bring an unduped iceman to 5 50 soon to help in war attack also. Below I've got 2 champs from each of the other classes and I'm not totally sure what I should do in each. I have none of the 4 stars in 5 star form. What would you do for each:

3-45 gulk unawakened
5 50 cap iw awakened

4 55 gwenpool unawakened
3 45 km unawakened

4 55 heimdall unawakened
3 45 venom unawakened

3 45 dr oc unawakened
5 50 sparky unawakened

3 45 hood unawakened
5 50 gr awakened