Go with STAR LORD mate.....he is easily the most useful to be awakened......starky does not need to be awakened.....he hits like a truck when you stack poise charges.....but Star Lord needs his ability at high level to do decent damage....
DH or starky or sentinel or SL. Quite a lol lol. Starky best overall, DH if you have a ton of stones, sentinel if you need double immune, SL if you need a good champ for LOL or stuff like that.
SL would benefit the most, in that, he is pretty useless without the dupe. That being said, I don't find Starlord that useful anymore, now in the age of evades, debuffs and timed fights (aw, aq).
So, I would do Sentinel or Sparky, as they have much more utility across content (now and future).
SL is still pretty good. Get combo up to 25 and land a sp2 with a fury and thats a kill shot in alot of situations. Plus he is a good choice for LOL if you have him at R3 or 4.
But for finesse purposes Sparky is a good choice too but doesn't need awakened
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So, I would do Sentinel or Sparky, as they have much more utility across content (now and future).
But for finesse purposes Sparky is a good choice too but doesn't need awakened
DH and IWIM aren't really useful defenders unless they're awoken; but DH needs a ton of sig stones dumped into him.
SL in general isn't really useful unless he's awoken - so he potentially benefits the most, BUT I don't think he's the most deserving.
Sentinel has the most utility, but Stark I'd say is probably the best choice.