Which Science Champion To Add?

I'm looking for input and advice on which of the following Science-Class Champions to upgrade for Act IV and beyond plus why that Champion should be prioritized over others? Note that all Champions are not yet Awakened.

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SupperHero4Sales

I'm amazed at all of his Synergy potential without even looking through possible External Synergies too. Also, I was unaware that he could counter Unstoppable although I am a fan of Perfect Block with select Defense Masteries reducing 100% of all Damage.

While my Yellow-Jacket whom is 5-Star (Non-Awakened) is truly amazing with Poison Sting often becoming Critical whenever an opponent activates their Special Attack; I need a strong alternate for when any top-tier Champions are busy with Alliance Quests and such.

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