Venom is amazing for variant 2. especially that last quest and how he just tears through everything. He's also a good counter against Spider-Gwen, which is very nice. All three of those characters will be amazing for your roster, though. Havok just has a ton of damage on his sp3 which is really nice, and Archangel just minces through champs as long as they aren't bleed- or poison-immune. His awakened ability probably also helps the most out of those three options you have there. He's worth a generic imo. The others... well you only really should use class gems on them.
Don't forget though that this is just a game, and it really comes down to who you want. Don't feel forced to make rankup decisions just because people tell you they're better (like how I wouldn't take a stark spidey up just because I don't enjoy playing him that much).
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All three of those characters will be amazing for your roster, though. Havok just has a ton of damage on his sp3 which is really nice, and Archangel just minces through champs as long as they aren't bleed- or poison-immune. His awakened ability probably also helps the most out of those three options you have there. He's worth a generic imo. The others... well you only really should use class gems on them.
Don't forget though that this is just a game, and it really comes down to who you want. Don't feel forced to make rankup decisions just because people tell you they're better (like how I wouldn't take a stark spidey up just because I don't enjoy playing him that much).