I have just completed Act 5 for the first time last week. At the moment. I am focusing on trying to Explore Act 5.
I just aquired the 2nd T5 basic needed to R5 a 5*. Who should I rank up?

I've been thinking it will be Doom but I don't know how useful he will be moving forward.
Even if I get a good 6* for my first one (in about 2 months at my current rate) I expect my 5*s will still be my primary focus for quite a while.
I have Skill/Science/Cosmic AG available, if that could be relevant to your answer.