I got a red awakening 3 years ago and got my nick fury just this summer. Use it for Nick since there's a chance that you won't have herc in the nearest future
I'd have to say Nick Fury as well. The benefit you get from him being awakened is crazy. Whereas Herc is still very solid unawakened. Obviously, awakening Herc is ideal but like others have said, who knows when you'll get him. You have Fury now & you can benefit from his Sig now. But hey, go with your gut. If you don't think you'll use Fury much, maybe waiting isn't such a bad option.
You might not get herc for a while, unless you are maybe saving like 15k units for cyber weekend hoping they will have the 2021 selector again but they might just have a generic in the deals as well, id go with nick
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Use it for Nick since there's a chance that you won't have herc in the nearest future