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Who to take to R4 6star?

Hi have the following… right now shang chi and dr doom duped are rank 3 6-star… the rest of the rank 2 i can easily rank 3… who among them should i take to my first R4 6 star? 
Leaning towards doom obviously

Leaning towards doom obviously
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Nimrod unduped is a sneaky battlegrounds r4 too, as he will appear low down.
Doom does not need it.