Next rank up

I'm looking for the next champion to 5/65 as a 5*, currently from the skill class. I've been waiting for someone like Nick Fury or Valkyrie but I also have some good options from my current roster.
Hit-Monkey, Kingpin, Black Widow (Deadly Origins), or Mole Man? Of these options, who should I max rank? None are awakened and I have no AG to give to anyone and BWDO is the only R4. Everyone else is R1 (for now).
My other max 5* are Infamous Iron Man, Kitty Pryde, and Dr Doom. Also here are all my other skill 5*

Hit-Monkey, Kingpin, Black Widow (Deadly Origins), or Mole Man? Of these options, who should I max rank? None are awakened and I have no AG to give to anyone and BWDO is the only R4. Everyone else is R1 (for now).
My other max 5* are Infamous Iron Man, Kitty Pryde, and Dr Doom. Also here are all my other skill 5*

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