Rank up to complete Act 5

Deandc43

Hey guys i am trying to complete act 5, i am already uncollected with the current 4* champs all awakened: Dr. Voodoo 5/50, Stark Spidey 5/50, Quake 5/50, Thor 5/50, Hyperion 5/50, Iceman 5/50, Cap wwii 5/50, Scarlet Witch 5/50, Star lord 5/50, Wolverine 5/50. I want to upgrade the best champ possible for completion of act 5 and for prestige. i have available for upgrade 5* Gambit 2/35 awakened, 5* Psylocke 2/35 Unawakened, 4* Archangel 4/40 Unawakened, 4* Vision 4/40 Awakened, 5* Star Lord 2/35 unawakened, 4* Ultron 4/40 Unawakened, 4* Rogue 3/30 Awakened, 5* Loki 1/25 Unawakened, 4* Doc Octopus 3/30 Awakened, 4* Green Goblin 3/30 Unawakened, 4* Morningstar 3/30 Unawakened, 5* Black panther CW 1/25 unawakened, 5* Agent Venom 1/25 unawakened, 5* Spiderman Miles Morales 1/25 unawakened. I use 4* Ultron, 4* Vision and 4* Scarlet Witch in AQ, 4* Thor, 4* Iceman and 4* Hyperion in AW.