So it has been a year and change since the Thronebreaker title arrived, and with it the Thronebreaker Daily Crystal. I've been recording every crystal opening to measure the drop odds for this crystal. It is a little late as I've been busy, but here's the first 365 days of TB Daily crystals.

In 365 days I opened 326 crystals. I didn't actually miss any days directly (I logged in every day). Rather, because the 24 hour timer restarts when you claim the crystal, the next one arrives later and later during the day until eventually one day it happens after I go to sleep, whereupon I effectively "lose" a crystal. 326 crystals means I'm only getting about 89% of them, and letting daily wrap around cost me a crystal about once every nine days or so. I could do better if I set an alarm or something, but I have no intention of doing that.
The one drop I have yet to get: 10k 6* shards. I just keep striking out there. But also curious: the last time I got T5CC fragments was on November 30, 2020. I've had three T5CC drops, all within the first two months. I appear to have been either super lucky initially, or super unlucky after that, or the odds have changed. Possibly all three.
Given my opening rate, factoring in the fact that I don't open one per day (I lose a few here and there), on average how much stuff have I been getting in an average 30 day month?

those 30 day averages are total amounts, not drops. In other words, I've been averaging about 6.4 T4B catalysts per month. That's not bad for free crystals, and competitive with other "free" sources of resources, such as the Thronebreaker calendar.
Assuming I'm seeing something close to the actual drop odds for the crystals, I would say the value in this crystals is appropriate for Thronebreaker freebees. The value is high enough to be interesting, every drop is at least useful, but the value isn't so high as to be game altering. It strikes a good balance between being valuable enough to be worth getting, but not so valuable that it is painful to lose one or two.
At this point I'm waiting to see how long before the 10k 6* shards. Is it a 500 to 1 drop, a 1000 to 1 drop, or am I just cursed. Hopefully I'll find out while 6* champs are still relevant to the game.
Trivia:
5* champs pulled to date: Korg, Dragon Man, Vulture
I've gotten the exact same drop three times in a row several times. I have yet to have the same drop four times in a row.
I've gotten at least one full T4CC of every class. The class I've had the most full catalyst drops, by far, is mutant (five). Skill, Science, and Tech are all tied at one.
If a player decided to claim these over time and then open them in bulk, they could open a year's worth of crystals in about twenty minutes total (between claiming and opening). A year's worth got me 90 units, which would have been 270 units per hour of time spent (had I not spent all this time logging everything). That's one of the best unit returns per minute you can get in the game (of course, it is unsustainable).