I got spidey og, he was not usefull, but i had shang chi, so he was a usefull synergy partner, he did well in the act 4 chaos paths whenever he got the precision buff.
1st 5* was Star Lord. Second was Magik and she was my first dupe, but I duped SL as well and he cleared so much content for me. Did LOL 100% with him. I have a duped 6* now and I'd love for him to get a buff.
Cyclops from the original 12-champ 5* crystal. He completed my perfect block team with 4* Black Bolt and 4* Magneto and was my dominant attacker until 12.0 came along.
I think I pulled Gambit as my first 5* champion. I ranked him up a bit but eventually used a rank-down ticket on him back when those were still a thing. (This was a looooong time ago.) This was years before his buff so he was pretty much just trash and I never used him much. I had a small roster of 4*s that carried me through the content until I eventually pulled good 5* champions. I was pretty lucky with pulling Captain America IW fairly early on and he would carry me through a ton of content.
My first 5*, Rocket Racoon. And despite being a champion with little utility, at that time he helped me a lot to progress in Act 4, mainly because of his good E2 damage and his defensive ability.
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But he wasn't my first 5*.
Thanks, Rocket!
2 words: Power control