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4* ascended vs 5* rank 5

So I ascended my 4* Dr Doom a long time ago (I didn’t have any 5* I could rank at the time so it was a case of use it or lose it). I’ve now pulled a 5* Dr Doom and I’m wondering if it is worth putting in the resources to rank him up. I don’t intend to ascend this one so I’m guessing it may not be worth it but would value any opinions.
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He helps you in the long run, also the more doom,the better.
I have ascended 5* Doom because I don't have him as 6* & it is easier to max sig him.
You can see him nestles among r4 6* like Human Torch & Nimrod and r1 7* like Sauron & Gamora.