Who to rank 5 as 4* tech champ

So I have 5 tech t4cc and now I'm just waiting on a few t4bc. I have all 3 champs at rank 4 duped. Doc Ock, Spider-Man Stark Enhanced, and Starlord. I've had Doctor Octopus for the longest and have gotten really good with him and I just got Spider-Man from arena earlier today. Who would you guys recommend to first bring up to rank 5.
Who to rank 5 as 4* tech champ 35 votes
Doctor Octopus
14%
5 votes
Starlod
34%
12 votes
Spider-Man Stark Enhanced
51%
18 votes
0
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