Block proficiency is nice, but not exactly viable. Besides the whole point of this game is to "not get hit" as they say. The raw damage output Hulk has puts him at least among the demi-god tier champions. He is an excellent choice for the collector.
For your Science class champ, top focus is HULK, follow by Void and Quake. Both the Cap AM (Classic & WWII) are good but you can upgrade them once you got the 3 upgraded. For AW Def, one of the top choice in Science class is MODOK, depending on your upgrade priority (Quest? AQ/AW attk? AW def? etc)
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