I pulled 5* DD Netflix twice in a row awhile back. It can happen my man. And the 6* pool is smaller so I think it'd be even more likely to pull what you did.
I just pulled a 5* Jane Foster followed immediately by a 6*. While I do truly believe in RNG, I have seen this happen a lot. I think it could be a glitch at times. Usually when I'm opening multiple, if I pull one I dislike I close and re open the game before opening another. Don't know how I forgot on my Jane Foster.
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but people have also won the lottery and the rng odds there are much worse...
First 6* was beast, 5* after that was beast, then within the same month, 4* beast lol