Who to rank up?

I’ve recently pulled a 6* Domino from compensation rewards!! I also have a 5* Cap MM, awakened, at rank 4. I am currently at 6.2.4., with the intention of doing Labyrinth after 6.2 completion. I have 5* Red Hulk for synergies (no massacre). Who should i take up? Cap MM would be my first r5, and Dom would be my first r2. Thanks y’all!

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