Which 5 star is the most rank up worthy?

I’m uncollected and am starting to build up a good 5 star roster to eventually go into late act 5 and act 6 for cavelier, which of these 5 stars that I have would help me the most in this late game content. For reference I already have NF duped at r4 and cap iw unduped at r3. All of the options below are unduped.

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Gr8TonyStark

Shehulk is great But you should wait for falcon buff

SpideyFunko

You don’t really need five stars for the rest of act 5. Four stars should get the job done.

TheBair123

Didn't mean Heimdall. Meant to click She-Hulk

Přìņče01

Or she hulk depending on your preference
I said thing coz he is still very good without synergy and he will be very useful in varient 2 as well

DannyB01

If you still have act 5 to explore, I think there's a good case for Venom the Duck. He's a pretty good path clearer, but She-Hulk will be more useful in act 6.

Colonaut123

Falcon should help you with Masochism, but wait till he´s fully released and tested.

Dfraga71388

She-hulk over VTD? Hell nah