Mr Fantastic's synergy with She Hulk is not applying power sting when a debut is applied. Not yet sure if it is all synergy members, or just her. Will update when tested.
I was having issues with the MrF + massacre synergy earlier as well. Expected it to pause Kingpin's buffs but no luck. Haven't tested with anyone else yet, but think you're right that Stretch's synergies appear to be bugged.
Team was just kingpin + stretch, both 6*, and massacre as 5* vs ROL winter soldier.
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Team was just kingpin + stretch, both 6*, and massacre as 5* vs ROL winter soldier.