I've obtained a slightly stupid number of 2016 Tech 3-4 Rank-up gems clearing Variant content, and I'm wondering which of these old-but-now-buffed champs to use them on:
- Hulkbuster
- Ultron
- War Machine
I haven't used them all that much post-buff, and could do with a bit of guidance.
For reference, I'm TB who doesn't run suicides, currently clearing in 7.3. I'm looking for champions to help out in 7.3/7.4; and other late-game content.
And I've a crazy stockpile of Sig Stones, if anyone really needs a high Sig.

I've already have Vision Awakened at r5, and Star Lord and Kang at r4, so don't need to save the Gems for those options.
I have two rank-up gems left. My questions are:
1: what are your thoughts on the respective utility/damage/synergy value of these three recently-buffed champions?
2: Assuming that r4 is a stepping stone to r5, would you prioritise ranking up the Awakened 5* or the Unawakened 6*?
Main choices:
5* Ultron (Sig 40)
6* Ultron
5* War Machine (Sig 40)
6* War Machine
5* Hulkbuster (Sig 40)