Gwenpool is just good overall, so probably yes. Only have a 3* variant myself, and not really into ROL (because I could never complete it), so not sure.
Just searched up ROL best champ options, and gwenpool isn't on there, so I don't know. But she's god tier, so... yeah.
You can definitely beat WS, just use enervate and keep hitting him, but she will take forever. If u have SL duped or Wolvie, they can carry u thru (assuming you have a Guilly or Void to take RoLWolvie
4/40 will certainly take a long time, but definitely doable (in fact i did it myself playing on my second account). The best strategy would be to use sp3 and maintain the infinite armor break. You will need to dupe her if you want to be wolvie tho, or bring guillotine.
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Just searched up ROL best champ options, and gwenpool isn't on there, so I don't know. But she's god tier, so... yeah.