Which 3 stars to rank up?

Hi,
I need your help with chose which one of my champions I should to rank up? I’m trying to finish Chapter 3.
3 star:
AntMan, Rhino, Uns. Colossus, SL, Groot, Volverine, Ultron, Thor JF, Elektra, Thor, BW, Hyperion, AV, Joe Fixit (Dup), Modok, Cull Obsidian, Nova, Inv. Woman, Annihilus, Doc. Octopus, Cap. Marvel, Loki, BP, Ms. Marvel, Hulk, Cap. Marvel, Punisher, Hawkeye (Dup), BP CW (Dup), Nightcrawler, Karnak, Sabretooth, Ronin, Vision, S-M SS, Rocket Raccon (Dup), Phoenix, Sentry (Dup), Psylocke (Dup), Ebony Maw (Dup), Human Torch, Angela (Dup)
4 stars: S-M (Stark), CA IW, Havok, Diablo, Old Man Logan, Sentinel, Cyclop, AV, Loki, Vulture, Ms. Marvel, BP

From 3 stars I have Gweenpool and Hulk Tagnarok ranked up at max but is insufficient for finish Chapter 3 or play in Chapter 4. So which of my 3 and 4 stars champions are the best ones in your opinion that I should rank them up at max?
Thanks

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