You need a champ who has the lowest odds pf being added as a 7*, which is Herc in your case. Apoc could be argued about, but since he is independant on his sig level, I would vote against, because a 7* will come one day.
Did you really just try to claim ascending the 5* is why you dont want to do the 6 star?
A max 5 star is about the same as an R2 (ascended is about R3 equivalent)... you can ascend an R5... twice the PI of your 5 star herc
the reason i isn’t want to do him is because my 5* is also max sig and it’s hard to get a 6* to r3 currently (i’m cav). I plan to rank up herc, but i’m just not sure if he’s worth ascending before i finish act 6
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A max 5 star is about the same as an R2 (ascended is about R3 equivalent)... you can ascend an R5... twice the PI of your 5 star herc
Diablo/kingpin is next but for You apoc