Proxima gets great value out of it if you need a long-fight champ by getting her ultimate mission. Hyperion and Medusa both gain a lot from their sig abilities as well. Personally, I'd say Hyperion or Proxima. I would lean towards Proxima, but that is partly because I use her frequently with Corvus. My rule of thumb for awakening gems is to use it on the champ intend to use the most or rank up the highest.
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