There is also a synergy between She-Hulk and Daredevil that increases stun duration for all champs in the team.
Are you referring to this one ? If so, it's not duration it increases .. just Ability accuracy % ...
What's a little odd about it is that neither She-Hulk nor Daredevil actually gain any benefit from that aspect of the synergy, as Shulk's SP1 no longer inflicts stun, her SP3 is 100%, and DD has 100% chance on special crits. So neither needs a boost to their stun chance . Unless they're fighting Domino, I suppose.
Helpful if you've got a teammate like Hulk, though.
Hulkbuster sp1. Why has nobody said Hulkbuster? His stun duration is not necessarily long BUT you still can chain stun it with power reserve. There is actually a way to make it longer. Make sure the opponent is holding block then you use sp1. More armor up buff on HB, the longer the duration is.
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Helpful if you've got a teammate like Hulk, though.
Starky has a synergy with these two to increase stun duration