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How regeneration of Scarlett witch works @.@

I'm totally confused about her regen. ability sometimes it works sometimes not. Can anyone tell me how it actually works ? O.O
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Her signature ability is that she has a chance to activate buffs when she or the opponent lands a critical hit, and regen is one of those buffs that is a bit rarer (I think at least). It's not going to be consistent, but it will still come. Try reading her description!
Key words:
Critical Hits
Chance
Buff and Debuff
Its a perk , not a guaranteed ability as SW is not a primary regen champ
Having her at sig 99 with max crit boost team does help quite a bit
All other occurrences are purely coincidental.