They all get a massive benefit from being awakened. What 5*s do you have that you could potentially take to 5/65? Because you might have some better options there (and you don't need to use as many t5b to take them up)
Cull is the only one that does not need to be awakened to be useful. And he kicks butt with or without it. Human torch isn't that great,fun to play but even awakened I wouldn't take him to rank 2. Nick fury if awakened could be a great rank 2,but he NEEDS to be awakened.
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I have a 6* un Awakened fury