I’d start with Diablo. I think you can get most of it out of iBom unawakened and you might pull a 6* that you could then take to act 7. An unawakened 6* Diablo would not be as good as your 5*.
Both are Poison Kings in their own right. Perhaps in terms of raw poison damage numbers iBomb has the edge over Diablo, but Diablo has other utilities in his kit such as nullify, a very reliable and sustainable self heal, more energy resistance, stun immunity, etc among others. IBomb, otoh, besides his face-melting (pun intended) poison damage he also has a reliable weakness and petrify which can be quite useful sometimes. So it's all an apples to oranges comparison, really.
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